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#426
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#427
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Marc Levenson - member of DFWMAS |
#428
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thanks Marc
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Nothing good happens fast in this realm of underwater landscaping, only time will allow your reefkeeping and livestock to flourish! |
#429
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Is there a test for sulphate?
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#430
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I think I may have bryopsis and another algae that is more like a "tumbleweed". The tumbleweed algae is easy to remove almost coming off the sand and rock in clumps.
The other patches on the live rock however...must be bryopsis. Tough to pinch out with your fingers and a more dense low growth. Here is a full tank shot showing the patches of algae. I had removed a good portion of the tumbleweed algae by hand. This is a "before" picture as I had a normal Mg level. I have been double dosing magnesium sulfate and have incresed the Mg to 1470ppm over the last week from about 1320ppm. I am just about out of the Seachem Reef Magnesium (ingredients listed as magnesium sulfate, sodium, chloride) so I will get some Tech M and try to zap this stuff!
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Sam |
#431
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You may try a fresh water test kit for sulphate with a range up to 200 ppm but you will need to dilute the sample 1:19 (1 sample and 19 RO/DI or distilled water) and multiply the result by 20.
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. |
#432
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Sammy the Seachem product is only around 10% magnesium sulfate, the other 90% is magnesium chloride, quite a few others on the thread have already discovered that magnesium chloride did nothing for the algae, regardless how high they took magnesium.
Dosing the Seachem product you may think you are dosing magnesium sulfate, but in fact you just cannot get enough magnesium sulfate in there, you are not shifting the ionic balance of the tank in favour of sulfate. Go with Tech M, or alternatively Epsom salts is 100% magnesium sulfate. Last edited by wilsonh; 09/20/2007 at 06:58 PM. |
#433
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If epsom salt is 100% magnesium sulphate, could you indirectly measure how much sulphate is being added by measuring the increase in mg?
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#434
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Yes but someone with more chemistry knowledge than me would have to give you the formula.
Perhaps the RC chemistry forum would be a good place to ask. |
#435
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Epsom Salts is Magnesium Sulfate Heptahydrate which is: MgSO4·7H2O whose molecular weight is 246.4 or 246.4 grams per mol.
Ot of this total 24.3 grams is Magnesium (9.9% Mg), 96.1 grams is Sulfate (39 % SO4) and the remining 126 grams is water (51.1% H2O) So the ratio by weight of Sulphate to Magnesium is 96.1 to 24.3 or 3.955 to 1 In other words for every 1 ppm of Magnesium you increase you will roughly increase Sulphate by 4 ppm. As Natural Sea Water contains about 2710 ppm of Sulfate it is possible to calculate the % increase in sulfate with a one shot increase of magnesium. This Table from one of Randy's article can give you a good comparison Magnesium Starting Sulfate Final Sulfate Sulfate Rise Boost (ppm)    (ppm)nbsp; (ppm) (%) 50 2710 2908 7% 100 2710 3105 15% 200 2710 3500 29% 300 2710 3895 44%
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. Last edited by jdieck; 09/21/2007 at 12:48 AM. |
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Hmmm... Impressive Jdieck!
Would also be interesting to find out the exact level sulfate has to be to do the job although that might be hard cos you would have to know the starting sulfate. And that is of course assuming that it actually is the sulfate that is killing the algae, although having read the whole thread & seeing what works for people it would seem that is likely. |
#437
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Quote:
http://reefkeeping.com/issues/2006-07/rhf/index.php
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. |
#438
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I used ESV liquid magnesium and Seachem Reef Advantage Magnesium, for 3 weeks 1600 mg/l, didn't worked. Still have bryosis. Resistant kind?
And, reading from the label on the Seachem Reef Mg, at the left: "...blend of magnesium, chloride, and sulphate salts....", on the right, very fine print: "Ingredients: Magnesium sulfate, sodium chloride". I too thought, that it is the blend of MgSo4 and MgCl2.... |
#439
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Given the ingredients, they are using Magnesium Sulfate but not Magnesium Chloride but instead they use Sodium Chloride. IMO as a Magnesium Supplement it has advantages and disadvantages. The advantage is that most contaminants specially Ammonia comes from the manufacturing of Magnesium Chloride so by not using it they insure higher purity, the cons is that they need to balance the increase in Shulphate with increases in Sodium and Chloride ions something they achieve by using Sodium Chloride but this creates one pro and two cons, the pro is that they will balance sodium which supplements with magnesium chloride will not but one of the cons will be that the product will be more dilute for Magnesium so more of it is required to achieve the same Mg increase than with a supplement that contains Mg Sulfate and Mg Chloride and the second is that in large corrections it might increase salinity a little bit but I doubt in an amount noticeable by most refractometers. So in summary it is better balanced, might be higher purity but will be more dilute. Regarding if it affects Bryopsis it will be imposible to know, at least at this point is seems that does not which leeads me to believe that the effect on bryopsis does not come from either sulfate nor chloride but rather either the magnesium level itself or some impurity in a particular supplement or a combination of both.
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. |
#440
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This will give a ratio of Sodium to Sulfate of about .24 to 1 when NSW is about 4:1 and a ratio of Chloride to Sulfate of 0.57 when the ratio in NSW is 7:1 If the formulation uses Magnesium Sulfate Anhydrous the ratio improves a little bit to 0.75:1 for Sodium:Sulfate and 1.16:1 for Chloride:Sulfate; still far from the required 4:1 and 7:1 to be fully balanced. On the other hand although a supplement containing a 10:1 mix of Mag Chloride and Mg Sulfate will not contain any sodium it will balance the Chloride to Sulfate on the required 7:1 ratio. In summary, in my opinion (and I might be wrong) although Seachem's contain some sodium and chloride ions and may reduce the risk of impurities the supplement is not necessarily better balanced than a 10:1 supplement of Mg Chloride and Mg Sulfate
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. |
#441
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I understood their formula was 10% magnesium sulfate, 90% magnesium chloride, no sodium chloride, making an ionically correct mix.
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#442
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. |
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No, I make my own, but when I did have the Seachem product they don't give the exact ingredients, presumably to stop someone realising how cheap the raw ingredients are compared to what they charge LOL!
I just read where someone claimed to have figured out what the mix is but long time ago I don't have a link. However a 10/90 mix Magnesium sulfate to Magnesium chloride would make sense as it does give the correct ionic balance that they claim on the jar label. |
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#445
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A regular formulation of those two will have a magnesium concentration of around 11.7% but Seachem's concentration is 7.97% which makes me think there is some ingridient that does not provide magnesium (like sodium chloride)
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. |
#446
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Did I write what I wrote? What the heck am I talking about! Well..... Nevermind. |
#447
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I just want to kill my Bryopsis.
COST & CHEMISTRY DISCUSSIONS ASIDE, is it the concensus that people using Tech M have had the best results against bryopsis, followed by the epsom salts method? Very interesting and informative thread, but I don't have the patience to go through all 445 posts. |
#448
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Tech M works. Get the mag up to 1500-1600.
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#449
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#450
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#@&*%# Test kit only goes to 1500!
Just plunked down 33 bucks for a Salifert test kit and it only goes to 1500. No problem yet since I am starting at 1300, but what do I do later?
Do I cut the amount of water, powder and indicator liquid in half, then perform the final step as directed and double the result from the chart? |
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