My RODI water does read 5 with a MH-COM100 TDS meter but as I understand it since this is just measuring conductivity that this is as low as you can probably get your tap water TDS using this type of test? Anyway the Meter is brand new factory calibrated.
If you are getting anything other than 0 or 1 ppm TDS from the DI, it is spent and silicate can be one of the first things to be released from a depleting DI.
I discuss those issues here:
Reverse Osmosis/Deionization Systems to Purify Tap Water for Reef Aquaria
http://reefkeeping.com/issues/2005-05/rhf/index.htm
from it:
In the DI descriptions above, I did not address the fact that some ions will show a greater preference for attachment to the resin than will others. When the resins are not depleted, it does not matter what the ions’ affinity is, as all are bound. But in a depleted scenario, when there are more ions than ion binding sites, those with a higher affinity for the resin will be retained, and those with a lower affinity will be released. It turns out that silicate is found at the lower end of affinity for anion resins. Consequently, if the DI resin has been collecting silicate for a long period and is then depleted, a large burst of silicate may be released.
and
Monitor the DI resins by measuring the effluent’s conductivity, either with an inline meter (set to its most sensitive level), or by measuring the effluent manually. If you are using a TDS or conductivity meter, then the measured value should drop to near zero, or maybe 0-1 ppm TDS or 0-1 mS/cm. Higher values indicate that something is not functioning properly, or that the DI resin is becoming saturated and needs replacement. That does not necessarily mean, however, that 2 ppm TDS water is not OK to use. But beware that the flow of impurities and the conductivity may begin to rise fairly sharply when the resin becomes saturated. Do not agonize over 1 ppm versus zero ppm. While pure water has a TDS well below 1 ppm, uncertainties from carbon dioxide in the air (which gets into the water and ionizes to provide some conductivity; about 0.7 mS/cm for saturation with normal levels of CO2, possibly higher indoors) and the conductivity/TDS meter itself may yield results of 1 or 2 ppm even from totally pure water by not being exactly zeroed properly. Also note that the first impurities to leave the DI resin as it becomes saturated may be things that you are particularly concerned with (such as ammonia if your water supply uses chloramine or silica if there is a lot in the source water).