hey mike,
re: stand...concrete counter top could work, as would a few layers of plywood....you could rib the underside for more strenth.
re:aquascaping, try making the right wall very open and you'll be fine. D&D epoxy and fiberglass or acrylic rod and you should be good to go.
i think it will look good. i would make the farthest right point of the arch very low, only a few inches tall.
who are you going with for the tank?
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